Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(II) complex

作者：Ni Chengbao; Stich Troy A; Long Gary J; Power Philip P^*

来源：Chemical communications, 2010, 46(25): 4466-4468.

DOI：10.1039/c001483d

The synthesis and characterization of two-coordinate cobalt(II) complexes CoAr(2)' (1) and Ar'CoN(SiMe(3))(2) (2) (Ar' = C(6)H(3)-2,6-(C(6)H(3)-2,6-(i)Pr(2))(2)) are reported. The magnetic data for 2 show that it has an unexpectedly high mu(eff) of 5.65 mu(B) whereas the bent complex 1 has a significantly lower moment.

• 出版日期2010