A novel porphyrin-homooxacalix[3] arene conjugate which creates a C-3-symmetrical capsular space

作者：Kawaguchi M; Ikeda A; Shinkai S^*

来源：Tetrahedron Letters, 2001, 42(22): 3725-3728.

DOI：10.1016/S0040-4039(01)00463-4

A novel capsular molecule in which three porphyrin-based building blocks are capped by two ionophoric calixarene molecules has been synthesized for the first time. The Zn(II) complex showed a high encapsulation ability for C-3-symmetrical guest molecules. In addition, the binding properties were allosterically controlled by added Na+ or CH3OH.

• 出版日期2001-5-28