A hydrogen bonded molecular capsule versus a 3D network of tripodal organopolysilanols

作者:Fukawa Marina; Sato Takayuki; Kabe Yoshio*
来源:Chemical Communications, 2015, 51(79): 14746-14749.
DOI:10.1039/c5cc04515k

摘要

1,3,5-Triethylbenzene based tripodal trisilanols were synthesized. The X-ray crystal structures of trisilanols showed capsule formation as well as non-capsular network formation using silanol hydrogen bonds. The H-1 NMR and ESI-mass spectroscopy experiments for solution state binding supported encapsulation of the halide ions in the cavity of the molecular capsule with a C-3 symmetry.

  • 出版日期2015