摘要
1,3,5-Triethylbenzene based tripodal trisilanols were synthesized. The X-ray crystal structures of trisilanols showed capsule formation as well as non-capsular network formation using silanol hydrogen bonds. The H-1 NMR and ESI-mass spectroscopy experiments for solution state binding supported encapsulation of the halide ions in the cavity of the molecular capsule with a C-3 symmetry.
- 出版日期2015