Novel reactivity of unconjugated diimines with [PtCl2(coe)](2) (coe=cis-cyclooctene)

作者：Derrah EJ; Zhang HW; Nikolcheva LG; Vogels CM; Decken A; Westcott SA^*

来源：Inorganic Chemistry Communications, 2003, 6(8): 1086-1090.

DOI：10.1016/S1387-7003(03)00193-X

• unconjugated diimines
• platinum
• boronate esters
• aminoboron

The addition of unconjugated diimines [ArC(H)=NCH2CH2N=C(H)Ar, L1: Ar = 3-C(6)H(4)Bpin (pin = 1,2-O2C2Me4), L2: Ar = 4-C(6)H(4)Bpin, and L3: Ar = 4-C6H4OMe] to [PtCl2(coe)](2) (coe = cis-cyclooctene) affords the corresponding dinuclear species [trans-PtCl2(coe)](2)L (1-3), where the diimine coordinates in a monodentate fashion to each of the metal centres. Compounds have been characterized by multinuclear NMR spectroscopy, FT-IR spectroscopy, elemental analyses, and for the case of 2, by X-ray diffraction.

• 出版日期2003-8