Mechanism of Selective Oxidations of Hydrocarbons with Hydrogen Peroxide Catalyzed by Metalloporphyrins

作者：Li Fengying^*; Liu Ye; Wang Xia; He Xiaoshuang; Ding Xia

来源：Progress in Chemistry, 2008, 20(11): 1635-1641.

• iron porphyrins
• manganese porphyrins
• selective oxidation
• mechanism
• hydrogen peroxide

Recent researches on mechanism of hydrocarbon selective oxidations with hydrogen peroxide catalyzed by metalloporphyrins including iron porphyrins and manganese porphyrins are reviewed in this paper. The strategies to promote heterolytic cleavage of hydrogen peroxide to facilitate the formation of active high valent metal-oxo species are discussed in detail.

• 出版日期2008-11
• 单位华东师范大学