A Recyclable Biphasic System for Stereoselective and Easily Handled Hydrochalcogenations

作者:Tidei Caterina; Sancineto Luca; Bagnoli Luana; Battistelli Benedetta; Marini Francesca; Santi Claudio*
来源:European Journal of Organic Chemistry, 2014, 2014(27): 5968-5975.
DOI:10.1002/ejoc.201402668

摘要

Vinyl selenides and vinyl sulfides were prepared by hydrochalcogenation of alkynes with selenols and thiols generated in situ by the reduction of the corresponding diselenides and disulfides with elemental zinc in a biphasic acidic medium. The yields, stereoselectivity as well as the possibility of reusing the aqueous medium up to ten times are discussed.

  • 出版日期2014-9
  • 单位Perugia