An integrated experimental and theoretical investigation on Cu(hfa)(2)center dot TMEDA: structure, bonding and reactivity

作者：Bandoli Giuliano; Barreca Davide^*; Gasparotto Alberto; Seraglia Roberta; Tondello Eugenio; Devi Anjana; Fischer Roland A; Winter Manuela; Fois Ettore; Gambae Aldo; Tabacchi Gloria

来源：Physical Chemistry Chemical Physics, 2009, 11(28): 5998-6007.

DOI：10.1039/b904145a

The physico-chemical properties of the beta-diketonate diamine Cu(II) compound with hfa (1,1,1,5,5,5-hexafluoro-2-4-pentanedionate) and TMEDA (N,N,N',N' tetramethylethylenediamine), Cu(hfa)(2)center dot TMEDA, have been thoroughly investigated via an integrated multi-technique experimental-computational approach. In the newly found orthorhombic polymorph, as revealed by low temperature single-crystal X-ray studies, the complex is present as a monomer with a distorted octahedral geometry at the Cu(II) centre. The compound sublimates, without premature side decompositions, at 343 K and 10(-3) Torr. The structural, vibrational, electronic and thermal behavior of the neutral Cu(hfa)(2)center dot TMEDA complex has been investigated along with its fragmentation pathways, initiated by the release of an anionic hfa ligand with formation of a positive Cu(hfa)center dot TMEDA( ) ion. Joint experimental and theoretical analyses led to the rationalization of the first fragmentation steps in terms of the Cu(II)-ligands bonding properties and Jahn-Teller distortion. The present study suggests applications of Cu(hfa)(2)center dot TMEDA as a precursor for copper and copper oxide materials by Chemical Vapor Deposition.

• 出版日期2009