科研之友
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摘要
Two types of alternating morphology transitions have been observed in crystallization of NH(4)Cl on agar plates. One is the alternating morphology transitions between dense branching morphology and sparse branching morphology, and the other is the alternating morphology transitions between dense branching morphology and zigzag branching morphology. The appearance of them is found to depend on the mass proportion of agar to NH(4)Cl in the initial solution and the relative humidity. It is suggested that both the two alternating morphology transitions result from the oscillation of solute concentration in front of the growing interface caused by the competition of crystal growth and solute transfer at a moderate mass proportion. Which one of them occurs depends on the relative humidity, which controls the supersaturation.
