An unprecedented (5,12)-connected 3D self-penetrating metal-organic framework based on dinuclear barium clusters as building blocks

作者：Xiao, Dongrong^*; Chen, Haiyan; Zhang, Guangju; Sun, Dianzhen; He, Jianghong; Yuan, Ruo; Wang, Enbo

来源：CrystEngComm, 2011, 13(2): 433-436.

DOI：10.1039/c0ce00622j

• COORDINATION NETWORKS
• HIGH CONNECTIVITY
• TOPOLOGY
• POLYMER
• CRYSTAL
• CHEMISTRY
• DESIGN
• ZINC
• NET
• INTERPENETRATION

An unprecedented binodal (5,12)-connected 3D self-penetrating metal-organic framework was first assembled from dinuclear barium clusters as 12-connected nodes and flexible ligands 4,4'-sulfonyldibenzoate as 5-connected nodes, and it represents the highest connected self-penetrating topology presently known for metal-organic frameworks.

• 出版日期2011
• 单位东北师范大学; 西南大学