科研之友
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摘要
The cation ordered perovskites Ba2Nd1-xYxMoO6 (0.04 %26lt;= x %26lt;= 0.35) have been synthesised by solid-state techniques under reducing conditions at temperatures up to 1350 degrees C. Rietveld analyses of X-ray and neutron powder diffraction data show that these compounds adopt a tetragonally distorted perovskite structure. The tetragonal distortion is driven by the bonding requirements of the Ba2+ cation that occupies the central interstice of the perovskite; this cation would be underbonded if these compounds retained the cubic symmetry exhibited by the prototypical structure. The size and charge difference between the lanthanides and Mo5+ lead to complete ordering of the cations to give a rock-salt ordering of Nd3+/Y3+O6 and MoO6 octahedra. The I4/m space group symmetry is retained on cooling the x=0.1, 0.2 and 0.35 samples to low temperature ca. 2 K. Ba2Nd0.90Y0.10MoO6 undergoes a gradual distortion of the MoO6 units on cooling from room temperature to give two long trans bonds (2.001(2) angstrom) along the z-direction and four shorter apical bonds (1.9563(13) angstrom) in the xy-plane. This distortion of the MoO6 units stabilises the 4d(1) electron in the d(xz) and d(yz) orbitals whilst the d(xy) orbital is increased in energy due to the contraction of the Mo-O bonds in the xy-plane. This bond extension along z is propagated through the structure and gives a negative thermal expansion of -13 x 10(-6) K-1 along c. The overall volumetric thermal expansion is positive due to conventional expansion along the other two crystallographic axes. With increasing Y3+ content this distortion is reduced in x=0.2 and eliminated in x=0.35 which contains largely regular MoO6 octahedra. The x=0.1 and x=0.2 show small peaks in the neutron diffraction profile due to long range antiferromagnetic order arising from ordered moments of ca. 2 mu(B).
- 出版日期2013-4
