An efficient method for the simultaneous determination of furan, 2-methylfuran and 2-pentylfuran in fruit juices by headspace solid phase microextraction and gas chromatography-flame ionisation detector

作者：Hu, Gaofei; Zhu, Yan; Hernandez, Marta; Koutchma, Tatiana; Shao, Suqin^*

来源：Food Chemistry, 2016, 192: 9-14.

DOI：10.1016/j.foodchem.2015.06.100

• 2-Alkylfrans
• Furan
• 2-Methylfuran
• 2-Pentylfuran
• Headspace solid phase microextraction
• GC-FID

A headspace solid phase microextraction (HS-SPME) procedure followed by gas chromatography-flame ionisation detector (GC-FID) analysis was developed and validated for the simultaneous analysis of furan, 2-methylfuran and 2-pentylfuran from juice samples. Extraction at 32 degrees C for 20 min with stirring at 600 rpm and NaCl concentration 15% (W/V) was the optimal HS-SPME condition for all the three compounds by using a carboxen/polydimethylsiloxane fused silica fibre (75 mu m). The extracted compounds were base line separated on a SPB-1 GC column within 12 min. The relative standard deviations of all analytes were less than 6.7%. The recovery rates were between 90.2% and 110.1%. The limits of detection and limits of quantification were 0.056-0.23 ng/mL and 0.14-0.76 ng/mL, respectively. The results showed that the developed method was sensitive, precise, accurate and robust for the determination of furan, 2-methylfuran and 2-pentylfuran in complex matrices without interferences from other components.

• 出版日期2016-2-1
• 单位北京化工大学