Direct synthesis of quinazolinones by acceptorless dehydrogenative coupling of o-aminobenzamide and alcohols by heterogeneous Pt catalysts

作者:Siddiki S M A Hakim*; Kon Kenichi; Touchy Abeda Sultana; Shimizu Ken ichi
来源:Catalysis Science & Technology, 2014, 4(6): 1716-1719.
DOI:10.1039/c4cy00092g

摘要

HBEA zeolite-supported Pt metal nanoclusters (Pt/HBEA) effectively catalyze direct dehydrogenative synthesis of quinazolinones from o-aminobenzamide and alcohols under promoter-free conditions. This is the first heterogeneous catalytic system for this reaction, which has a turnover number (TON) more than 25 times higher than previous homogeneous catalysts as well as wide scope for aliphatic and aromatic alcohols.

  • 出版日期2014