A 2D Zn(II) coordination polymer constructed by right-handed and left-handed Zn-Hbci-Zn helical chains and mu(2)-H2O bridges (H(3)bci = bis(2-carboxyethyl)isocyanurate)

作者：Liang Yan Fang; Wang Xiao Fang^*; Zhang Guo xin; Han Zheng Bo

来源：Inorganic Chemistry Communications, 2011, 14(7): 1107-1110.

DOI：10.1016/j.inoche.2011.03.072

• Coordination polymer
• Helical chains
• mu(2)-H2O bridges
• Photoluminescence properties

Reaction of Zn(OAc)(2)center dot 2H(2)O and bis(2-carboxyethyl)isocyanurate (H(3)bci) leads to the generation of a new coordination polymer, Zn(Hbci)(H2O)(3) (1), (H(3)bci=bis(2-carboxyethyl)isocyanurate), which features an interesting 2D layer containing Zn(II)-Hbci-Zn(II) right-handed and left-handed helical chains and mu(2)-H2O bridges. Furthermore, hydrogen bonds link the adjacent 2D layers to form a 3D supramolecular framework. The photoluminescence property of 1 was also studied.

• 出版日期2011-7
• 单位辽宁大学