Measurement of Interaction Parameter between Cu and Al in Molten High Al Steel

作者:Sugiyama Kengo; Ueda Shigeru*; Gao Xu; Kim Sunjoong; Kitamura Shin ya
来源:ISIJ International, 2017, 57(4): 625-629.
DOI:10.2355/isijinternational.ISIJINT-2016-676

摘要

The interaction parameter between Cu and Al in molten iron containing high levels of Al was measured using a chemical equilibrium technique. A molten Fe Al alloy was equilibrated with a molten Ag-Cu alloy in an Al2O3 crucible at 1 823 K. The activity coefficient of Cu in Fe Al alloys was measured to be -2.33 while varying the concentration of Al in a range from 0.04-0.2 mol%. The influence of Cu on the deoxidation equilibrium of Al and O was estimated using the above interaction parameter. The results indicate that under a constant Al concentration, a contamination of several percent of Cu raises the O concentration in high Al steel.

  • 出版日期2017