Adsorptive Properties of Novel Nanoporous Materials

作者：Noguchi Hiroshi; Kondo Atsushi; Noguchi Daisuke; Kim Dong Young; Ohba Tomonori; Yang Cheol Min; Kanoh Hirofumi; Kaneko Katsumi^*

来源：Journal of Chemical Engineering of Japan, 2007, 40(13): 1159-1165.

DOI：10.1252/jcej.07WE211

• Adsorption
• Gas Storage
• Nanoporous Solid
• Carbon Nanotube
• MOF

New nanoporous materials and fundamental concepts on molecule solid interaction are introduced. The nanopore structures of single wall carbon nanotube (SWCNT), single wall carbon nanohorn (SWCNH), double wall carbon nanotube (DWCNT), and highly flexible Cu-complex crystals as a representative of metal organic frameworks (MOFs) are explained. Adsorption properties of SWCNT, SWCNH, and DWCNT for supercritical CH4, and H-2, and Cu-complex crystals for supercritical CH4, are shown. DWCNT has a better adsorption potential for supercritical H-2, than SWCNT. The Cu-complex crystals form very quickly a new clathrate compound with CH4, molecules on adsorption of CH4, the reproducible clathrate formation is sensitive to temperature.

• 出版日期2007