Activation of B-H bonds by an oxo-rhenium complex

作者：Fernandes Ana C^*; Fernandes Jose A; Almeida Paz Filipe A; Romao Carlos C

来源：Dalton Transactions, 2008, (47): 6686-6688.

DOI：10.1039/b816802b

The isolation and structural characterization by X-ray diffraction of (PPh3)(2)(O)(I) Re(H)OBcat 1 and (PPh(3))(2)(O)-(I)Re(H)OBpin 2 from the reaction of ReIO(2)(PPh(3))(2) with the boranes catecholborane (HBcat) and pinacolborane (HBpin) unequivocally shows the first example of activation of B-H bond by a high valent oxo-rhenium complex.

• 出版日期2008