mu-Oxido-bis[bis(pentafluorophenolato)(eta(5)-pentamethylcyclopentadieny l)titanium(IV)]

作者：Lee Junseong; Kim Youngjo^*

来源：Acta Crystallographica Section E-Structure Reports Online, 2011, 67: M1147-U1286.

DOI：10.1107/S1600536811029357

The dinuclear title complex, [Ti-2(C10H15)(2)(C6F5O)(4)O], features two Ti-IV atoms bridged by an O atom, which lies on an inversion centre. The Ti-IV atom is bonded to eta(5)-pentamethylcyclopentadienyl ring, two pentafluorophenolate anions and to the bridging O atom. The environment around the Ti-IV atom can be considered as a distorted tetrahedron. The cyclopentadienyl ring is disordered over two sets of sites [site occupancy = 0.824 (8) for the major component].

• 出版日期2011-8