An interesting recyclization in the course of reduction of 1-(2-nitro-4-R-phenyl)-1H-benzimidazoles with tin(II) chloride

作者:Begunov Roman S*; Shebunina Tatyana V; Yakovleva Yulia S; Firgang Sergey I
来源:Mendeleev Communications, 2013, 23(6): 354-355.
DOI:10.1016/j.mencom.2013.11.018

摘要

Reduction of 1-(2-nitro-4-R-phenyl)-1H-benzimidazoles with tin(H) chloride in an acidic water alcohol medium is accompanied by unusual recyclization of 1-(2-amino-4-R-phenyl)-1H-benzimidazoles formed at the first stage into isomeric 1-(2-aminopheny1)-5-R- 1H-benzimidazoles.

  • 出版日期2013-12

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