A variety of solid-state fluorescence properties of pyrazine dyes depending on terminal substituents

作者：Hirosawa Risa; Akune Yoko; Endo Natsuko; Hatano Sayumi; Hosokai Takuya; Sato Hiroyasu; Matsumoto Shinya

来源：Dyes and Pigments, 2017, 146: 576-581.

DOI：10.1016/j.dyepig.2017.07.055

• Solid-state fluorescence
• Substituent effect
• Heavy atom effect
• 2,5-diamino-3,6-dicyanopyrazine

The optical properties of 2,5-diamino-3,6-dicyanopyrazine derivatives bearing singly methyl- or halogen-substituted benzyl groups were studied in both solution and crystalline phases. In solution, all derivatives showed similar absorption and fluorescence properties, since the electronic state of their fluorophore was not altered by substituents attached to the benzyl groups. In contrast, crystalline compounds exhibited a variety of fluorescence colours (yellow, orange, and red), since their solid-state absorption and fluorescence properties were correlated with a change in the electron-donating ability of amino groups due to crystallisation. The absolute fluorescence quantum yields of crystalline dyes (0.14-0.91) showed broad variability, depending on the nature and positions of terminal substituents.

• 出版日期2017-11