Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: synthesis, structures and multi-centre bonding interactions at the M-Si-H-Si four-membered ring

作者:Hashimoto Hisako*; Komura Katsuto; Ishizaki Takatoshi; Odagiri Yuto; Tobita Hiromi*
来源:Dalton Transactions, 2017, 46(27): 8701-8704.
DOI:10.1039/c7dt00505a

摘要

Hydrogen-bridged bis(silylene) complexes of ruthenium and iron were synthesized as the first examples of this type containing Group 8 metals and their rare four-membered ring structures and multi-center bonding interactions at the M-Si-H-Si moiety were clarified by NMR spectroscopy, X-ray crystallography and theoretical calculations.

  • 出版日期2017-7-21