Branched Co3O4/Fe2O3 nanowires as high capacity lithium-ion battery anodes

作者：Wu Hao; Xu Ming; Wang Yongcheng; Zheng Gengfeng^*

来源：Nano Research, 2013, 6(3): 167-173.

DOI：10.1007/s12274-013-0292-z

• Co3O4
• alpha-Fe2O3
• nanowire
• branched
• lithium-ion battery
• Nyquist plot

We report a facile, two-step hydrothermal synthesis of a novel Co3O4/alpha-Fe2O3 branched nanowire heterostructure, which can serve as a good candidate for lithium-ion battery anodes with high Li+ storage capacity and stability. The single-crystalline, primary Co3O4 nanowire trunk arrays directly grown on Ti substrates allow for efficient electrical and ionic transport. The secondary alpha-Fe2O3 branches provide enhanced surface area and high theoretical Li+ storage capacity, and can also serve as volume spacers between neighboring Co3O4 NW arrays to maintain electrolyte penetration as well as reduce the aggregation during Li+ intercalation, thus leading to improved electrochemical energy storage performance.

• 出版日期2013-3
• 单位复旦大学