Anion-specific aggregation induced phosphorescence emission (AIPE) in an ionic iridium complex in aqueous media

作者：Li, Guangfu; Guan, Wei; Du, Shuang; Zhu, Dongxia^*; Shan, Guogang; Zhu, Xiaojuan; Yan, Likai; Su, Zhongmin; Bryce, Martin R.; Monkmand, Andrew P.

来源：Chemical communications, 2015, 51(95): 16924-16927.

DOI：10.1039/c5cc07187a

• FLUORESCENCE TURN-ON
• DELAYED FLUORESCENCE
• CELLS
• LIGANDS
• WATER

Efficient aggregation induced phosphorescence emission (AIPE) of an ionic Ir(III) complex occurs when the counterion (PF6-) is exchanged specifically by ClO4- in aqueous media. As a result, a rapid, highly selective "turn-on'' phosphorescent response to ClO4- is observed in aqueous media. These studies pave the way for a new efficient phosphorescence-based detection strategy for anions.

• 出版日期2015
• 单位东北师范大学