Luminescence, magnetic and vibrational properties of novel heterometallic niccolites [(CH3)(2)NH2][(CrMII)-M-III(HCOO)(6)] (M-II=Zn, Ni, Cu) and [(CH3)(2)NH2][(AlZnII)-Zn-III(HCOO)(6)]:Cr3+

作者：Maczka Miroslaw; Pietraszko Adam; Pikul Adam; Hermanowicz Krzysztof

来源：Journal of Solid State Chemistry, 2016, 233: 455-462.

DOI：10.1016/j.jssc.2015.11.027

• Metal organic framework
• Magnetization
• Luminescence
• Infrared
• Raman

Abstract(#br)We report synthesis of three novel heterometallic MOFs, [(CH 3 ) 2 NH 2 ][Cr III M II (HCOO) 6 ] with M=Zn (DMCrZn), Ni (DMCrNi) and Cu (DMCrCu), crystallizing in the niccolite type structure. We also successfully synthesized [(CH 3 ) 2 NH 2 ][AlCu(HCOO) 6 ] (DMAlCu) and [(CH 3 ) 2 NH 2...

• 出版日期2016-1
• 单位Polish Academy of Sciences