Deuterium Exchange Study for Hydrogenation of D-5-1-Pentene (4,4,5,5,5) Over Conventional Cobalt Fischer-Tropsch Catalyst

作者：Gnanamani Muthu Kumaran; Shafer Wilson D; Davis Burtron H^*

来源：Catalysis Letters, 2012, 142(2): 190-194.

DOI：10.1007/s10562-011-0750-8

• Deutero-1-pentene
• Hydrogenation
• Fischer-Tropsch
• Cobalt
• Deuterium exchange

The hydrogen-deuterium exchange reaction was performed for hydrogenation of D-5-1-pentene (4,4,5,5,5) under realistic cobalt Fischer-Tropsch synthesis conditions. In the presence of CO, the added deutero-1-pentene did not show any significant H/D exchange but a step-wise H/D exchange occurs when CO was replaced with N-2. The inhibition effects of CO and other FT products on H/D exchange of D-5-1-pentene and a pressure dependency effect on H/D exchange are observed.

• 出版日期2012-2