(Z)-4-(2-Naphthylamino)pent-3-en-2-one

作者:Harrad Mohamed Anoir; Boualy Brahim; Oudahmane Abdelghani; Avignant Daniel; Rizzoli Corrado*
来源:Acta Crystallographica Section E-Structure Reports Online, 2011, 67: O1818-U1800.
DOI:10.1107/S1600536811024494

摘要

The title compound, C15H15NO, which was synthesized under solvent-free conditions by the reaction of acetoacetone and 2-naphthylamine, adopts a Z conformation about the C=C bond. The enamine-ketone fragment is approximately planar [maximum deviation = 0.026 (3) angstrom] and forms a dihedral angle of 39.78 (3)degrees with the naphthalene ring system. An intramolecular N-H center dot center dot center dot O hydrogen bond is observed.

  • 出版日期2011-7