An unprecedented 2D → 3D metal-organic polyrotaxane framework constructed from cadmium and a flexible star-like ligand

作者：Wu, Hua; Liu, Hai-Yan; Liu, Ying-Ying; Yang, Jin^*; Liu, Bo; Ma, Jian-Fang

来源：Chemical communications, 2011, 47(6): 1818-1820.

DOI：10.1039/c0cc04724d

• DIMENSIONAL COORDINATION POLYMER
• 2-DIMENSIONAL POLYROTAXANE
• NETWORK
• INTERPENETRATION
• ENTANGLEMENT
• CUCURBITURIL
• 1,4-BIS(IMIDAZOL-1-YLMETHYL)BENZENE
• COVALENT
• PARALLEL
• CRYSTAL

An unprecedented 2D -> 3D metal-organic polyrotaxane framework, based on a new star-like tri(4-imidazolylphenyl)-amine ligand, has been synthesized and characterized, which represents the first example of 2D -> 3D polyrotaxane entangled in a parallel fashion.

• 出版日期2011
• 单位东北师范大学