A novel Cd-II coordination polymer with 1,1 '-(1,4-butanediyl)diimidazole

作者：Ma JF^*; Yang J; Liu JF

来源：Acta Crystallographica Section C-Crystal Structure Communications, 2003, 59: M482-M483.

DOI：10.1107/S0108270103022443

The novel title Cd-II coordination polymer, poly[[dichlorocadmium(II)]-di-mu-1,1'-(1,4-butanediyl)diimidazole], [CdCl2(C10H14N4)(2)](n), (I), was obtained by reaction of CdCl2.2.5H(2)O and 1,1'-(1,4-butanediyl)diimidazole (hereafter L). In (I), each L molecule coordinates to two Cd-II cations through its two aromatic N atoms, thus acting as a bridging bidentate ligand. The Cd-II cations, which lie on the inversion centre, are bridged by four L molecules to form a two-dimensional (4,4)-network. The two-dimensional square-grid sheets are superimposed in an offset fashion.

• 出版日期2003-11
• 单位东北师范大学