A metal-organic framework with rod secondary building unit based on the Boerdijk-Coxeter helix

作者：Xiao, Qiong; Wu, Yuan; Li, Mian; O'Keeffe, Michael^*; Li, Dan^*

来源：Chemical communications, 2016, 52(77): 11543-11546.

DOI：10.1039/c6cc04912e

• CARBON-DIOXIDE CAPTURE
• MINIMAL TRANSITIVITY
• DIRECT VISUALIZATION
• TOPOLOGICAL ANALYSIS
• RETICULAR CHEMISTRY
• CRYSTAL-STRUCTURES
• NETS
• DESIGN
• SEPARATION
• NANOTUBES

The renowned aperiodic Boerdijk-Coxeter helix is identified, with a modified, periodic form, in a MOF named ROD-1 [formulated as Cd(L), H2L = (3,5-dimethyl-1H-(pyrazol-4-yl)-methylene) benzoic acid], which exhibits unusual gas adsorption behaviours attributed to guest-guest interactions, and also interesting structural dynamics responding to temperature variation and gas adsorption.

• 出版日期2016
• 单位暨南大学; 汕头大学