Microscopic models of mode-coupling theory: The F-12 scenario

作者：Arenzon Jeferson J^*; Sellitto Mauro

来源：Journal of Chemical Physics, 2012, 137(8): 084501.

DOI：10.1063/1.4746695

We provide extended evidence that mode-coupling theory (MCT) of supercooled liquids for the F-12 schematic model admits a microscopic realization based on facilitated spin models with tunable facilitation. Depending on the facilitation strength, one observes two distinct dynamical glass transition lines-continuous and discontinuous-merging at a dynamical tricritical-like point with critical decay exponents consistently related by MCT predictions. The mechanisms of dynamical arrest can be naturally interpreted in geometrical terms: the discontinuous and continuous transitions correspond to bootstrap and standard percolation processes, in which the incipient spanning cluster of frozen spins forms either a compact or a fractal structure, respectively. Our cooperative dynamical facilitation picture of glassy behavior is complementary to the one based on disordered systems and can account for higher-order singularity scenarios in the absence of a finite temperature thermodynamic glass transition. We briefly comment on the relevance of our results to finite spatial dimensions and to the F-13 schematic model.

• 出版日期2012-8-28