Preparation of organic nanoscrews from simple porphyrin derivatives

作者:Ozawa Hiroaki*; Tanaka Hirofumi; Kawao Masahiro; Uno Shigeyasu; Nakazato Kazuo
来源:Chemical communications, 2009, (47): 7411-7413.
DOI:10.1039/b915832d

摘要

Twisted supramolecular assemblies "nanoscrews'', were prepared by using simple porphyrin derivatives and acetonitrile solvent. The electrical properties of the assemblies were measured by using microgap electrodes. The nanoscrew had conductivity and showed photo-current. By changing the solvent, the pitch of the screws and their aggregation shapes could be controlled.

  • 出版日期2009