Activated carbon fibers as an effective metal-free catalyst for peracetic acid activation: Implications for the removal of organic pollutants

作者：Zhou Fengya; Lu Chao; Yao Yuyuan^*; Sun Lijie; Gong Fei; Li Daiwen; Pei Kemei; Lu Wangyang; Chen Wenxing

来源：Chemical Engineering Journal, 2015, 281: 953-960.

DOI：10.1016/j.cej.2015.07.034

• Activated carbon fibers
• Peracetic acid
• Alkoxyl radicals
• Metal-free catalyst

The development of an efficient and green catalytic system for recalcitrant pollutant removal is an attractive yet challenging research topic in the field of environmental catalysis. In the present work, the use of activated carbon fibers (ACFs) as a novel and excellent metal-free catalyst is proposed for peracetic acid (PAA) activation, constructing a pro-environmental and efficient catalytic system for the removal of organic pollutants. In this system, ACFs could effectively activate PAA to remove the dye Reactive Brilliant Red X-3B (RR X-3B) over a wide pH range (3-11), exhibiting a remarkable pH-tolerant performance. Moreover, the ACFs also displayed excellent sustained catalytic ability and regeneration capability, avoiding secondary contamination. A hybrid method that combines various radical scavengers with electron paramagnetic resonance (EPR) technology has been used to confirm that both hydroxyl radicals (HO center dot) and alkoxyl radicals (CH3C(O)O-center dot) were generated in the ACFs/PAA catalytic system. Furthermore, a combination of EPR with density functional theory calculations has been employed to evaluate the role of ACFs in the ACFs/PAA system. The results suggested that the introduction of ACFs facilitated homolytic cleavage of the O-OH bond, resulting in the generation of HO center dot and CH3C(O)O-center dot for the effective removal of organic dyes. Based on these results and analyses, a possible mechanism is proposed.

• 出版日期2015-12-1
• 单位浙江理工大学