A 3D Metal-organic Framework Containing [Cd(3-CPOA)](n) (3-CPOA(2-)=3-Carboxyphenoxyacetato Dianion) Expanded by 4,4 '-Bipyridine

作者：Deng Zhao Peng; Huo Li Hua; Gao Shan^*; Zhao Hui

来源：Zeitschrift fur Anorganische und Allgemeine Chemie, 2010, 636(5): 835-839.

DOI：10.1002/zaac.200900374

• Coordination polymers
• Hydrothermal synthesis
• Cadmium
• 3-Carboxyphenoxyacetatic acid
• Topology

The hydrothermal reaction of Cd(NO3) 4H(2)O with 4,4 bipyridine (bipy) and 3 carboxyphenoxyacetatic acid (3 H(2)CPOA) afforded 3D metal organic framework (MOF) [Cd(3 CPOA)(bipy)](n) 3 5nH(2)O which was characterized by elemental analyses, IR spectroscopy thermogravimetric analyses, and X ray diffraction The single crystal structural analysis revealed that It has a Cds type topological network with ID channels that contain encapsulated water molecular tapes

• 出版日期2010
• 单位黑龙江大学