Fabrication of Nitrogen-Doped Carbon Nanofiber Networks for Oxygen Reduction Reaction

作者：Meng, Shiming; Yu, Mei^*; Liu, Jianhua; Li, Songmei

来源：International Journal of Electrochemical Science, 2017, 12(6): 5404-5410.

DOI：10.20964/2017.06.12

• Oxygen reduction reaction
• polypyrrole
• networks
• carbon
• paralysis

In this work, nitrogen-doped carbon nanofiber networks (NCFWs) were fabricated by a simple method of paralyzing polypyrrole nanofiber networks (PPy NFWs) precursor. Scanning electron microscopy (SEM), Transmission electron microscopy (TEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) were employed to investigate the microstructure and composition of the as-prepared sample. Then the nitrogen-doped carbon nanofiber networks was further evaluated for its performance on Oxygen reduction reaction (ORR) with Cyclic voltammograms (CVs) and Linear sweep voltammograms (LSVs). The results showed that the fabricated NCFWs exhibited more remarkable catalytic performance compared with nitrogen-doped carbon nanoparticles (NFPs). Thus this material could be used as a better candidate in the field of fuel cells and metal-air batteries. The pyrolysis and structure of the NCFWs has obvious influence on their enhenced ORR properties.

• 出版日期2017-6
• 单位北京航空航天大学