Hydrogen desorption and absorption properties of Pd and MgO or nano-sized Ni-added MgH2 + LiBH4 composites

作者：Hong Seong Hyeon; Song Myoung Youp^*

来源：Materials Research Bulletin, 2013, 48(9): 3453-3458.

DOI：10.1016/j.materresbull.2013.05.030

• Hydrides
• Metals
• Electron microscopy
• X-ray diffraction
• Energy storage

In order to increase the hydrogen storage capacity of Mg-based materials, LiBH4 with a higher hydrogen storage capacity of 18.4 wt% was added to MgH2. Pd and MgO or nano-sized Ni were added to improve the desorption rate and decrease the desorption temperature of MgH2 and LiBH4 composite. Composite powders with compositions of 69.7 wt% MgH2 + 30.3 wt% LiBH4, 84 wt% MgH2 + 15 wt% LiBH4 + 1 wt% Pd, 79 wt% MgH2 + 15 wt% LiBH4 + 1 wt% Pd + 5 wt% MgO, and 79 wt% MgH2 + 15 wt% LiBH4 + 1 wt% Pd + 5 wt% Ni were prepared by planetary ball milling under hydrogen. The absorption and desorption properties of the samples were then examined. Among these samples, 79 wt% MgH2 + 15 wt% LiBH4 + 1 wt% Pd + 5 wt% Ni showed the highest desorption rate and the largest released hydrogen quantity, releasing 4.70 wt% H for 50 min, and 5.70 wt% H for 300 min. Among these samples, 84 wt% MgH2 + 15 wt% LiBH4 + 1 wt% Pd showed the highest absorption rate and the largest absorbed hydrogen quantity, absorbing 5.3 wt% H for about 25 min, and absorbing hydrogen even after 550 min, in particular. 84 wt% MgH2 + 15 wt% LiBH4 + 1 wt% Pd exhibited a relatively high desorption rate.

• 出版日期2013-9