A high-spin square-planar Fe(II) complex stabilized by a trianionic pincer-type ligand and conclusive evidence for retention of geometry and spin state in solution

作者：Pascualini M E; Di Russo N V; Thuijs A E; Ozarowski A; Stoian S A; Abboud K A; Christou G; Veige A S^*

来源：Chemical Science, 2015, 6(1): 608-612.

DOI：10.1039/c4sc02634a

Square-planar high-spin Fe(II) molecular compounds are rare and the only three non-macrocyclic or sterically-driven examples reported share a common FeO4 core. Using an easily modifiable pincer-type ligand, the successful synthesis of the first compound of this type that breaks the FeO4 motif was achieved. In addition, we present the first evidence that geometry and spin state persist in solution. Extensive characterization includes the first high-field EPR and variable field/ temperature Mossbaur spectra for this class of compounds. Analysis of the spectroscopic data indicates this complex exhibits a large and positive zero-field splitting tensor. Furthermore, the unusually small Delta EQ value determined for this compound is rationalized on the basis of DFT calculations.

• 出版日期2015