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摘要
In the crystal structure of the title compound, [Mn(C10H14O4)(C12H8N2)(H2O)(2)]center dot 3H(2)O, the Mn-II atom is in a distorted octahedral geometry, being coordinated by two N atoms of one 1,10-phenanthroline ligand, two O atoms from two carboxylate groups of the chelating cyclohexane-1,1'-diacetate dianion and two O atoms of two trans water molecules. The complex molecules are linked to form a three-dimensional network by hydrogen-bonding interactions between coordinated water molecules, non-coordinated water molecules and carboxylate groups of neighbouring molecules, and by aromatic pi-pi stacking interactions of the phenthroline rings.
- 出版日期2005-7
- 单位杭州师范大学
