Design and synthesis of nucleobase-incorporated metal-organic materials

作者:Zhang, Muwei*; Lu, Weigang; Li, Jian-Rong; Bosch, Mathieu; Chen, Ying-Pin; Liu, Tian-Fu; Liu, Yangyang; Zhou, Hong-Cai
来源:Inorganic Chemistry Frontiers, 2014, 1(2): 159-162.
DOI:10.1039/c3qi00042g

摘要

Two nucleobase-incorporated metal-organic materials were designed, synthesized and structurally characterized. PCN-530 is among the few examples of metal-organic frameworks that utilize adenine as a constructional unit, while TMOP-1 is the first existing example of a crystallographically characterized nucleobase-incorporated metal-organic polyhedron. This work also offers a general perspective for the design and synthesis of nucleobase-incorporated metal-organic materials.