An Fe-based MOF constructed from paddle-wheel and rod-shaped SBUs involved in situ generated acetate

作者:Li Yun Wu; Zhao Jiong Peng; Wang Li Fu; Bu Xian He*
来源:CrystEngComm, 2011, 13(20): 6002-6006.
DOI:10.1039/c1ce05470h

摘要

An Fe-based MOF has been constructed from a paddle-wheel-like dimeric Fe-cluster and a rod-shaped sinusoidal-like Fe-chain as two distinct secondary building units. Topological analyses indicate that this compound is a tetranodal (3,3,4,8)-connected net, which represents a new structural topology in MOFs. Moreover, the magnetic properties of 1 have been thoroughly investigated.