A novel macrocyclic organotin carboxylate containing a penta-nuclear long ladder

作者：Sougoule, Aboubacar Sidiki; Mei, Zemin; Xiao, Xiao; Balde, Cheick Abdoul; Samoura, Salematou; Dolo, Arouna; Zhu, Dongsheng^*

来源：Journal of Organometallic Chemistry, 2014, 758: 19-24.

DOI：10.1016/j.jorganchem.2014.01.034

• Organotin (IV) compound
• Synthesis
• Crystal structure
• Antitumor activity

A novel macrocyclic organotin carboxylate [(n-Bu2SnO)(5)L] (complex 1) [H2L = (3-carboxymethoxy-phenoxy) acetic acid] was synthesized by the reaction of di-n-butyltin oxide with H2L and is characterized by elemental analyses i.e. IR H-1 NMR and UV spectroscopies. X-ray crystallography diffraction analysis reveals that complex 1 is a centrosymmetric macrocycle and contains a penta-nuclear four-fold-ladder-like organo-oxotin cluster. All five Sn atoms are five-coordinated and the coordination environment can be considered as a trigonal bipyramidal. The luminescent property of complex 1 has also been investigated. Pilot studies have confirmed that complex 1 has shown good antitumor activity.

• 出版日期2014-5-15
• 单位白城师范学院; 东北师范大学