A Novel 2D Tubular Polymer Based on Flexible Bis-Methylbenzimidazole Ligand

作者：Xu Chunying; Wang Xianjuan; Guo Qianqian; Li Chuntong; Hou Hongwei^*; Fan Yaoting

来源：Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 2012, 42(5): 741-745.

DOI：10.1080/15533174.2011.615783

• flexible
• photoluminescence
• tubular channel

A novel metal-organic polymer [Cd(bmb)(p-bdc)](n) (1) (bmb =(1,4-bis(2-methylbenzimidazol-1-ylmethyl) benzene); p-H(2)bdc= p-benzenedicarboxylic acid) has been hydrothermally synthesized and structural characterized. Crystal data: 1, monoclinic, space group C2/c, a = 22.786(5) angstrom, b = 15.712(3) angstrom, c = 18.305(4) angstrom, beta = 18.305(4)degrees, Z = 4. Polymer 1 exhibits a 2D puckered layer structure with two different elongated tubular channels. In addition, the thermal stability, PXRD pattern, and photoluminescence properties of 1 in the solid state have also been investigated.

• 出版日期2012
• 单位郑州大学