Study of molecular interaction between some primary alcohols and anilines using concentration dependent dielectric properties

作者：Prajapati A N; Rana V A^*; Vyas A D

来源：Indian Journal of Pure & Applied Physics, 2013, 51(2): 104-111.

• Bruggeman parameter
• Excess static dielectric constant
• Fluoro substituted anilines
• Hydrogen bonding
• Molecular ineraction

The static dielectric constant (epsilon(0)) and optical dielectric constant (epsilon(infinity) = n(2)) of binary mixtures of some lower order primary alcohols with aniline, 2-fluoroaniline and 4-fluoroaniline over the concentration range (0.0, 0.1,.... 1.0) by volume fractions are measured at fix frequency 2 MHz using precision LCR meter and Abbe's refractometer, respectively. The excess dielectric constant, ICirkwood correlation parameter and Bruggeman parameter have been evaluated. The variations of these parameters with composition indicate the presence of molecular interaction between the participating components in these mixtures.

• 出版日期2013-2