A novel luminescent 3D metal-organic framework possessing 4-fold interpenetrating (3,4)-connected net

作者：Xu Guang Juan; Zhao Ya Hui; Shao Kui Zhan; Yuan Gang; Su Zhong Min^*; Yan Li Kai

来源：Inorganic Chemistry Communications, 2009, 12(10): 969-971.

DOI：10.1016/j.inoche.2009.07.023

• Coordination polymer
• 3,5-Bis(pyridin-4-ylmethoxy)benzoic acid
• Crystal structure
• Photoluminescent property

A novel 3D polymer [Zn(L(1))(1,4-BDC)(0.5)] (1) (HL(1) = 3,5-bis(pyridin-4-ylmethoxy)benzoic acid, 1,4-BDC = 1,4-benzenedicarboxylate anion) has been isolated under hydrothermal condition and characterized by single crystal X-ray diffraction. Compound I displays a 3D 4-fold interpenetrating (3.4)-connected net with (4 . 8(2))(4 . 8(5)) topology. In addition, powder X-ray diffraction, photoluminescent property and thermogravimetric analysis for I are investigated in detail.

• 出版日期2009-10
• 单位东北师范大学