Aqua(dicyanamido){mu-6,6 '-dimethoxy-2,2 '-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}copper(II)sodium(I )

作者:Shen Yong Miao; Wang Wei*
来源:Acta Crystallographica Section E-Structure Reports Online, 2009, 65(4): M472-U1155.
DOI:10.1107/S1600536809011064

摘要

The molecule of the title compound, [CuNa(C(18)H(18)N(2)O(4))(C(2)N(3))(H(2)O)], is almost planar, the maximum deviation from the molecular plane being 0.48 (4) angstrom. The coordination environment of the Cu(2 ) ion is distorted square-planar and it is N(2)O(2)-chelated by the Schiff base ligand. The Na( ) cation has a distorted octahedral environment defined by the four O atoms of the 6,6'-dimethoxy-2,2'-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolate ligand, a water ligand and a dicyanamide anion.

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