Densities and Viscosities for Binary and Ternary Mixtures of 2-Methylbutan-2-ol (1) + Trichloroethylene (2) + Acetonitrile (3) at 298.15 K and at Ambient Pressure (81.5 kPa)

作者：Iloukhani Hossein^*; Giahshenas Masoomeh; Khanlarzadeh Kh

来源：Journal of Solution Chemistry, 2013, 42(10): 1949-1959.

DOI：10.1007/s10953-013-0090-y

• Excess molar volume
• Viscosity deviation
• Excess Gibbs energy of activation
• 2-Methylbutan-2-ol
• Trichloroethylene
• Acetonitrile

Densities (rho) and viscosities (eta) of ternary mixtures of 2-methylbutan-2-ol (1) + trichloroethylene (2) + acetonitrile (3) and the related binary mixtures of {2-methylbutan-2-ol (1) + trichloroethylene (2)}, {2-methylbutan-2-ol (1) + acetonitrile (3)}, and {trichloroethylene (2) + acetonitrile (3)} have been measured over the whole composition range at 298.15 K and at ambient pressure (81.5 kPa). Excess molar volumes , viscosity deviations Delta eta, and excess Gibbs energies of activation Delta G (*E) were derived from the experimental data. The binary and ternary data of , Delta eta, and Delta G (*E) for the binary and ternary mixtures were correlated as functions of the mole fraction by using the Redlich-Kister and the Cibulka equations. Kinematic viscosities of the binary mixtures were correlated by means of several semi-empirical equations to determine the fitting parameters and the SDs. The experimental results are analyzed to discuss the nature and strength of intermolecular interactions in these mixtures.

• 出版日期2013-10