A ruthenium carbonyl cluster containing a hydroquinone ligand: A layered structure with a polymetallic species. Structure and electrochemical characterization

作者：Benito Pelayo Vazquez J; Gonzalez Felipe J^*; Leyva Marco A; Campos Myriam; Alfonso Torres Luis; Rosales Hoz Maria J

来源：Journal of Organometallic Chemistry, 2012, 716: 289-293.

DOI：10.1016/j.jorganchem.2012.06.030

• Ruthenium cluster
• Hydroquinone
• Intermolecular contacts
• Electrochemical
• Electrode inhibition

The reaction of [Ru-3(CO)(12)] with 1,4-benzoquinone, in a hydrogen atmosphere led to the formation of a product with the formula [(mu-H)Ru-3(CO)(10)(mu(2)-O-C6H4OH)] which crystallizes with two molecules of free hydroquinone in the asymmetric unit with which it forms an arrangement of hydrogen bridges leading to a layered structure of trinuclear metallic and hydroquinone fragments. Electrochemical studies showed that electrode inhibition is obtained by cycling of the oxidation process of this compound.

• 出版日期2012-10-1