An octupolar bis(porphyrinato) terbium(III) complex with the highest off-resonant hyperpolarizability

作者：Sun, Junshan; Han, Yinfeng^*

来源：RSC Advances, 2017, 7(37): 22855-22859.

DOI：10.1039/c7ra03033a

• NONLINEAR-OPTICAL PROPERTIES
• GIANT QUADRATIC HYPERPOLARIZABILITY
• 2-PHOTON ABSORPTION PROPERTIES
• DOUBLE-DECKER COMPLEXES
• RARE-EARTH COMPLEXES
• FREQUENCY DISPERSION
• LIGHT-SCATTERING
• METAL-COMPLEXES
• BASIS-SET
• CHROMOPHORES

A novel bis(porphyrinato) terbium double-decker complex HTb(DADAPor)(2) with a twisted cuboid octupolar molecular symmetry exhibits the largest off-resonant first hyperpolarizability, as evaluated by harmonic light scattering measurements with root(beta(2)(HLS))(1907) =1700 x(-30) esu.

• 出版日期2017
• 单位泰山学院