A continued fraction resummation form of bath relaxation effect in the spin-boson model

作者：Gong, Zhihao^*; Tang, Zhoufei; Mukamel, Shaul; Cao, Jianshu; Wu, Jianlan

来源：Journal of Chemical Physics, 2015, 142(8): 084103.

DOI：10.1063/1.4913198

• ELECTRON-TRANSFER
• ENERGY-TRANSFER
• 2-LEVEL SYSTEM
• QUANTUM SYSTEM
• DYNAMICS
• APPROXIMATION
• TRANSITION
• SOLVATION

In the spin-boson model, a continued fraction form is proposed to systematically resum high-order quantum kinetic expansion (QKE) rate kernels, accounting for the bath relaxation effect beyond the second-order perturbation. In particular, the analytical expression of the sixth-order QKE rate kernel is derived for resummation. With higher-order correction terms systematically extracted from higher-order rate kernels, the resummed quantum kinetic expansion approach in the continued fraction form extends the Pade approximation and can fully recover the exact quantum dynamics as the expansion order increases.

• 出版日期2015-2-28
• 单位浙江大学