(6-Hydroxy-2-{[2-(N-methylcarbamothiolyl)hydrazin-1-ylidene-kappa N-2(1),S]methyl}phenolato-kappa O-1)(triphenylphosphane-kappa P)nickel(II) chloride

作者：Shawish Hana Bashir; Maah M Jamil^*; Ng Seik Weng

来源：Acta Crystallographica Section E-Structure Reports Online, 2010, 66: M1366-U286.

DOI：10.1107/S1600536810039292

The deprotonated Schiff base ligand in the title salt, [Ni(C9H10N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated nickel(II) atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O-H center dot center dot center dot O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis.

• 出版日期2010-11