Morphological, structural, and magnetic properties of Co nanoparticles in a silicon oxide matrix

作者：Diaz M; Martinez L; Ruano M M; Llamosa P D; Roman E; Garcia Hernandez M; Ballesteros C; Fermento R; Cebollada A; Armelles G; Huttel Y^*

来源：Journal of Nanoparticle Research, 2011, 13(10): 5321-5333.

DOI：10.1007/s11051-011-0518-5

• Cobalt
• Nanoparticles
• Silicon
• Oxide
• Matrix
• Particle-wall interaction
• Particle agglomeration

We present a morphological, structural, and magnetic characterization of Co nanoparticles (mean diameter of 10.3 +/- A 1.8 nm) grown using a gas aggregation source and embedded in a silicon oxide matrix by sequential deposition of nanoparticles and silicon oxide. We show that the Co nanoparticles "soft-land" on the substrates and suffer a moderate oxidation in contact with the silicon oxide. Despite this moderate oxidation, it is found that, at room temperature, the magnetic volume of the resulting nanoparticles is below the superparamagnetic limit. The results presented in this article are compatible with the presence of an assembly of magnetically independent particles that also display a moderate exchange bias at low temperature.

• 出版日期2011-10