Preparation of Functionalized Lithium, Magnesium, Aluminum, Zinc, Manganese, and Indium Organometallics from Functionalized Organic Halides

作者：Dagousset Guillaume; Francois Cyril; Leon Thierry; Blanc Romain; Sansiaume Dagousset Elodie; Knochel Paul^*

来源：Synthesis (Germany), 2014, 46(23): 3133-3171.

DOI：10.1055/s-0034-1378672

• organometallic reagents
• functional groups
• organic halides
• metal insertion
• halogenmetal exchange

An overview of the most significant synthetic methods currently available for the preparation of functionalized organometallic compounds starting from organic halides is presented and illustrated with recent applications. 1Introduction 2Metal Insertion 2.1Magnesium 2.2Aluminum 2.3Zinc 2.4Indium 2.5Manganese 3HalogenMetal Exchange 3.1Lithium 3.2Magnesium 3.3Zinc 4Conclusion

• 出版日期2014-12